It happened Thursday afternoon in Scottsdale at a Safeway store's parking lot near Hayden and Chaparral.
Police say they were tracking the suspects they believed were tied in with an organized credit card fraud ring.
The video shows the suspect vehicle parking and officers surrounding the vehicle. The suspect tries to back up and ram his way out and injure the officers. The officers opened fire on the suspect and the vehicle comes to a rest.
"We can't choose the time and place when we take people into custody," said a Scottsdale Police spokesperson.
Investigators believe this ring is responsible for over $100,000 in fraudulent charges in the Phoenix area.